Publications

2019-1993

2024

"Iron complexes supported by silyl-NHC chelate ligands: synthesis and use for double hydroboration of nitriles"

T. Komuro,* K. Hayasaka, K. Takahashi, N. Ishiwata, K. Yamauchi, H. Tobita, H. Hashimoto*

Dalton Trans. 2024, 53, 4041. (DOI: doi.org/10.1039/d3dt03605g)

"Iron complexes supported by silyl-NHC chelate ligands: synthesis and use for double hydroboration of nitriles"

T. Komuro*, K. Hayasaka, K. Takahashi, N. Ishiwata, K. Yamauchi, H. Tobita, H. Hashimoto*

Dalton Trans. 2024, 53, 4041. (DOI: doi.org/10.1039/D3DT03605G)

"Reactions of Neutral Chromium Silylyne Complex with Alkynes and Butadiene: Access to Homoaromatic Compounds and Silacyclopentenyl Complexes"

M. Matsuoka, K. Nagata, R. Ohno, T. Matsuo, H. Hashimoto*

Chem. Lett. 2024, 53, upea002. (DOI: doi.org/10.1093/chemle/upae002)

2023

"Neutral Chromium Complex with a Cr≡Si Triple Bond: Synthesis and Photoinduced H–H and Benzene C–H Bond Activation"

M. Matsuoka, K. Nagata, R. Ohno, T. Matsuo, H. Tobita, H. Hashimoto*

Chem. Eur. J. 2023, e202303765.DOI: doi.org/10.1002/chem.202303765)

"Π-Character of Chromium Germylyne Complex in the Reactions with Enone, Butadiene, and Alkynes: Formation of Germacycles through [2+4] Cycloaddition with Conjugated Molecules"

K. Nagata, H. Omura, H. Hashimoto*

Chem. Asian J. 2023, e202300801.DOI: doi.org/10.1002/asia.202300801)

"Neutral Silylyne Complex of Molybdenum: Synthesis, Properties, and Access to Silaiminoacyl Complexes via [2+3] Cycloaddition"

H. Hashimoto*, K. Watanabe, T. Yoshimoto, N. Hayakawa, T. Matsuo, H. Tobita

Chem. Eur. J. 2023, e202302470.DOI: doi.org/10.1002/chem.202302470)

Selected as VIP (Very Important Paper)

"C–H and H–H Bond Activation by a Cationic Germylyne Complex"

T. Watanabe*, Y. Miyazaki, K. Inomata, H. Tobita, H. Hashimoto*

Organometallics 2023, 42, 846–858. (DOI: 10.1021/acs.organomet.3c00139.)

"Photoinduced One-pot Synthesis of a Chromium Germylyne Complex and Its Formation Mechanism"

K. Nagata, H. Omura, M. Matsuoka, H. Tobita, H. Hashimoto*

Organometallics 2023, 42, 1131-1138. (DOI: 10.1021/acs.organomet.2c00594.)

2022

"Recent progress in transition metal complexes supported by multidentate ligands featuring group 13 and 14 elements as coordinating atoms"

T. Komuro, Y. Nakajima,* J. Takaya,* H. Hashimoto,*

Coord. Chem. Rev., 2022,473, 214837. (DOI: 10.1016/j-ccr.2022.214837.)

"Iridium Complexes with a Naphthyridine-Based Si,N-Ligand: Synthesis and Catalytic Activity toward Olefin Hydrogenation"

K. Sato, T. Komuro,* T. Osawa, H. Hashimoto,* H. Tobita,

Organometellics 2022, 41, 2612–2621. (DOI: org/10.1021/acs.organomet.2c00373).

"Iridium and rhodium complexes bearing a silyl-bipyridine pincer ligand: synthesis, structures and catalytic activity for C–H borylation of arenes"

T. Komuro,* D. Mochizuki, H. Hashimoto,* H. Tobita,

Dalton Trans.2022,51, 9983–9987. (DOI: 10.1039/d2dt01227h).

2021

"Catalysts for Regio- and Stereoselective C(sp3)−H Deuteration of Tricyclohexylphosphine with Benzene‐d6 Generated via Dehydrochlorination of Chlorido(dihydrido)iridium Complexes Containing a Xanthene-Based Bis(silyl) Chelate Ligand"

T. Komuro,* J. Asagami, H. Higashi, K. Sato, H. Hashimoto,* H. Tobita

Organometallics, 2021,40, 3113-3123. (DOI: 10.1021/acs.organomet.1c00359).

"Transition-metal Complexes with Triple Bonds to Si, Ge, Sn, and Pb and Relevant Complexes"

H. Hashimoto *, K. Nagata

Chem. Lett. 2020, 50, 778-787. (DOI: doi: 10.1246 / cl.200872).

Selected as "Highlight Review" and "Inside Cover"

2020

"Synthesis of a Molybdenum Hydrido (hydrogermylene) Complex and Its Conversion to a Germylene Complex: Another Route through Dehydrogenation with Nitriles"

TP Dhungana, H. Hashimoto *, M. Ray, H. Tobita *

Organometallics 2020, 39 , 4350-4361 (DOI: 10.1021 / acs.organomet.0c00518).

"Bifunctional Rhodium Complex Featuring a Silyl–1,8-Naphthyridine Si, N-Chelate Ligand: Cooperation of Metal and Pendant Base for Capture and Bond-Weakening of BH3"

K. Sato, T. Komuro *, H. Hashimoto *, H. Tobita

Chem. Lett. 2020, 49 , 1431-1434 (DOI: 10.1246 / cl.200489).

"Products of [2 + 2] Cycloaddition between a W≡Si Triple-bonded Complex and Alkynes: Isolation, Structure, and Non-classical Bonding Interaction"

T. Yoshimoto, H. Hashimoto *, M. Ray *, N. Hayakawa, T. Matsuo, J. Chakrabarti, H. Tobita *

Chem. Lett. 2020, 49, 311-314 (DOI: 10.1246 / cl.190952).

Hashimoto Lab.

Inorganic Chemistry

PUBLICATIONS

2019-1993

2024

"Iron complexes supported by silyl-NHC chelate ligands: synthesis and use for double hydroboration of nitriles"

"Iron complexes supported by silyl-NHC chelate ligands: synthesis and use for double hydroboration of nitriles"

"Reactions of Neutral Chromium Silylyne Complex with Alkynes and Butadiene: Access to Homoaromatic Compounds and Silacyclopentenyl Complexes"

2023

"Neutral Chromium Complex with a Cr≡Si Triple Bond: Synthesis and Photoinduced H–H and Benzene C–H Bond Activation"

"Π-Character of Chromium Germylyne Complex in the Reactions with Enone, Butadiene, and Alkynes: Formation of Germacycles through [2+4] Cycloaddition with Conjugated Molecules"

"Neutral Silylyne Complex of Molybdenum: Synthesis, Properties, and Access to Silaiminoacyl Complexes via [2+3] Cycloaddition"

"C–H and H–H Bond Activation by a Cationic Germylyne Complex"

"Photoinduced One-pot Synthesis of a Chromium Germylyne Complex and Its Formation Mechanism"

2022

"Recent progress in transition metal complexes supported by multidentate ligands featuring group 13 and 14 elements as coordinating atoms"

"Iridium Complexes with a Naphthyridine-Based Si,N-Ligand: Synthesis and Catalytic Activity toward Olefin Hydrogenation"

"Iridium and rhodium complexes bearing a silyl-bipyridine pincer ligand: synthesis, structures and catalytic activity for C–H borylation of arenes"

2021

"Catalysts for Regio- and Stereoselective C(sp3)−H Deuteration of Tricyclohexylphosphine with Benzene‐d6 Generated via Dehydrochlorination of Chlorido(dihydrido)iridium Complexes Containing a Xanthene-Based Bis(silyl) Chelate Ligand"

"Transition-metal Complexes with Triple Bonds to Si, Ge, Sn, and Pb and Relevant Complexes"

2020

"Synthesis of a Molybdenum Hydrido (hydrogermylene) Complex and Its Conversion to a Germylene Complex: Another Route through Dehydrogenation with Nitriles"

"Bifunctional Rhodium Complex Featuring a Silyl–1,8-Naphthyridine Si, N-Chelate Ligand: Cooperation of Metal and Pendant Base for Capture and Bond-Weakening of BH3"

"Products of [2 + 2] Cycloaddition between a W≡Si Triple-bonded Complex and Alkynes: Isolation, Structure, and Non-classical Bonding Interaction"

2019-1993